Anion recognition in water with use of a neutral uranyl-salophen receptor
Antonella Dalla Cort1, Gianpiero Forte, Luca Schiaffino
1Department of Chemistry and IMC-CNR, Università La Sapienza, Piazzale Aldo Moro 5, 00185 Roma, Italy. antonella.dallacort@uniroma1.it
Abstract:
A new water-soluble uranyl-salophen complex incorporating two glucose units has been synthesized. This neutral derivative shows noteworthy binding affinity for fluoride in water thanks to the Lewis acid-base interaction occurring between the metal and the anion. Such interaction is strong enough to overcome the high hydration enthalpy of fluoride. Moreover this complex effectively binds hydrogen phosphate and exhibits remarkably strong association for nucleotide polyanions ADP(3-) and ATP(4-).
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