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Updated: May 30, 2026

Measuring Magnetically-Tuned Ferroelectric Polarization in Liquid Crystals
Published on: August 15, 2018
Determination of the orientational order parameter of a binary mixture showing an induced smectic A(d) phase from
Prithwi Dev Roy1, Banani Das, Malay Kumar Das
1Department of Physics, North Bengal University, Siliguri 734013, India.
Abstract:
The diamagnetic susceptibility anisotropy (Δχ) measurement of a binary mixture comprising of a strongly polar mesogen (CPPCC) and a weakly polar mesogen (ME6O.5) showing an induced smectic A(d) phase is reported here. Assuming an axially symmetric molecule, the temperature dependence of the orientational order parameter ⟨P(2)⟩ has been investigated from the anisotropy of the susceptibility at different temperatures throughout the entire composition range. The results are compared with x-ray and optical birefringence measurements along with the mean-field theory of the smectic A phase. The maximum in the stability of the smectic A(d) phase (at x(CPPCC) = 0.33) corresponds to the minimum in the order parameter values. The order of the smectic to nematic phase transition has also been discussed.
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