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Updated: May 30, 2026
08:46
Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
(Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide
Normen Peulecke1, Stephan Peitz, Bernd H Müller
1Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29A, 18059 Rostock, Germany.
Acta Crystallographica. Section E, Structure Reports Online
|August 13, 2011
Abstract:
The title compound, C(16)H(21)NP(+)·I(-), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P-N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor-acceptor N-H⋯I inter-action is observed.
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