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Analysis and discrimination of electrical tapes: part II. Backings
Andria H Mehltretter1, Maureen J Bradley, Diana M Wright
1Laboratory Division, Federal Bureau of Investigation, 2501 Investigation Parkway, Quantico, VA 22135, USA. andria.mehltretter@ic.fbi.gov
Forensic analysis of electrical tape backings using multiple techniques like FTIR and Py-GC/MS can effectively distinguish between samples. Combining these methods offers high discrimination rates for tape backing identification.
Area of Science:
- Forensic Science
- Materials Science
- Analytical Chemistry
Background:
- Electrical tapes are common in various settings, including crime scenes.
- Characterizing tape backings is crucial for forensic investigations.
- Previous studies focused on adhesive analysis, leaving backing characterization less explored.
Purpose of the Study:
- To evaluate chemical components of electrical tape backings.
- To assess the discriminatory power of individual analytical techniques.
- To determine the combined effectiveness of techniques for sample distinction.
Main Methods:
- Stereomicroscopy and physical measurements (surface features, width, thickness).
- Fourier transform infrared spectroscopy (FTIR) with a microscope accessory.
- Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS).
- Scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDS).
Main Results:
- Individual techniques showed varying discrimination capabilities: Stereomicroscopy (c. 64%), FTIR (c. 83%), Py-GC/MS (c. 81%), SEM/EDS (c. 87%).
- A combination of these analytical methods achieved 94% discrimination of tape backings.
- Integrating backing analysis with prior adhesive data yielded an overall discrimination of nearly 96%.
Conclusions:
- Multiple analytical techniques provide robust discrimination of electrical tape backings.
- Combined analysis of tape backings and adhesives offers superior forensic identification.
- This comprehensive approach enhances the evidential value of electrical tape analysis.
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