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Updated: May 29, 2026
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(III) luminescent
Christophe Lincheneau1, Carole Destribats, Dawn E Barry
1School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, Dublin, 2, Ireland.
Abstract:
The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH(3)CN give rise to the formation of lanthanide luminescent 'half-helicates' in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.
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