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Wilkinson's iridium acetate trimer as a water-oxidation catalyst

Alexander R Parent1, James D Blakemore, Gary W Brudvig

  • 1Yale University, Department of Chemistry, PO Box 208107, New Haven, Connecticut 06520-8107, USA.

Chemical Communications (Cambridge, England)
|September 29, 2011
PubMed
Summary

Wilkinson's iridium acetate trimer shows catalytic water-oxidation activity. It functions as a homogeneous catalyst with sodium periodate but decomposes rapidly with cerium(IV).

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