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Updated: May 29, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Carbohydrate-based pseudo-dipeptides: new ligands for the highly enantioselective Ru-catalyzed transfer hydrogenation
Mercedes Coll1, Oscar Pàmies, Hans Adolfsson
1Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Campus Sescelades, C/Marcellí Domingo, s/n, 43007 Tarragona, Spain.
Abstract:
Ruthenium-complexes of novel carbohydrate based pseudo-dipeptide ligands effectively and selectively catalyze the reduction of a broad range of aryl-alkyl ketones under ATH conditions. Excellent enantioselectivities (>99% ee) are obtained using aminosugars as the sole source of chirality.
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