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Updated: May 28, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Photorelease of primary aliphatic and aromatic amines by visible-light-induced electron transfer
Joseph B Edson1, Liam P Spencer, James M Boncella
1Materials, Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
Abstract:
Visible-light-absorbing tris(bipyridyl)ruthenium(II) has been used to mediate electron transfer to N-methylpicolinium carbamates that undergo C-O bond fragmentation followed by spontaneous carbon dioxide release to give free amines. Release of several aliphatic and aromatic primary amines has been demonstrated under mild conditions using visible light.
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