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Updated: May 27, 2026
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
2-(4-Chloro-phen-yl)-3,5-dimethyl-1λ,2-thia-zine-1,1-dione
Abstract:
In the title compound, C(12)H(12)ClNO(2)S, the S atom is displaced by 0.708 (2) Å out of the plane through the remaining atoms of the thia-zine ring (r.m.s. deviation = 0.0823 Å). This plane makes a dihedral angle of 89.33 (7)° with the phenyl ring. In the crystal, adjacent mol-ecules are connected through C-H⋯O hydrogen bonds into layers parallel to the bc plane.
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