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Updated: May 27, 2026
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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Stepwise syntheses of tri- and tetraphosphaporphyrinogens
Duncan Carmichael1, Aurélie Escalle-Lewis, Gilles Frison
1Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique and CNRS, 91128 Palaiseau cedex, France. Duncan.Carmichael@polytechnique.edu
Chemical Communications (Cambridge, England)
|November 18, 2011
Abstract:
A double ring-expansion methodology allows the stepwise synthesis of tri- and tetra-phosphaporhyrinogens. Structural and calculational methods reveal extended delocalisation about their phospholide centres.
