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Updated: May 27, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
catena-Poly[[trimethyl-tin(IV)]-μ-3,5-difluoro-benzoato-κO:O']
1College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Abstract:
In the title compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxyl-ate ligands. The five-coordinate Sn atom exists in a distorted trigonal-bipyramidal geometry with the mol-ecules connected by weak C-H⋯F inter-moleclar inter-actions, forming supra-molecular chains parallel to [010].
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