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Updated: May 27, 2026

Removal of Arsenic Using a Cationic Polymer Gel Impregnated with Iron Hydroxide
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Dipotassium disulfanilamidate trihydrate.

Fiona N-F How, Z A Rahima, Hamid Khaledi

    Acta Crystallographica. Section E, Structure Reports Online
    |November 18, 2011
    PubMed
    Summary

    This study details the crystal structure of a potassium sulfanilamidate compound. The structure reveals polymeric sheets formed by ions and water molecules, linked by various hydrogen bonds.

    Area of Science:

    • Crystallography
    • Inorganic Chemistry
    • Materials Science

    Background:

    • Sulfanilamide derivatives are important in medicinal chemistry.
    • Understanding the crystal structure of potassium sulfanilamidate provides insights into its properties and potential applications.

    Purpose of the Study:

    • To elucidate the crystal structure of the title compound, 2K(+)·2C(6)H(7)N(2)O(2)S(-)·3H(2)O.
    • To characterize the coordination environment of potassium cations and the hydrogen bonding network.

    Main Methods:

    • Single-crystal X-ray diffraction was used to determine the crystal structure.
    • Analysis of intermolecular interactions, including hydrogen bonds and C-H···π interactions.

    Main Results:

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  • The asymmetric unit contains two potassium cations, one sulfanilamidate anion, and 1.5 water molecules.
  • Potassium cations exhibit distinct coordination numbers and environments (seven- and eight-coordinate).
  • The crystal structure features polymeric sheets in the bc plane, consolidated by various hydrogen bonds and C-H···π interactions, forming a 3D network.
  • Conclusions:

    • The detailed crystal structure of potassium sulfanilamidate was determined.
    • The study highlights the role of hydrogen bonding and coordination in stabilizing the 2D and 3D structures.
    • Findings contribute to the understanding of supramolecular assembly in organic-inorganic hybrid compounds.