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Updated: May 27, 2026

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Published on: February 10, 2014
Charge trapping by self-assembled monolayers as the origin of the threshold voltage shift in organic field-effect
Fatemeh Gholamrezaie1, Anne-Marije Andringa, W S Christian Roelofs
1Molecular Electronics, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands; Philips Research Laboratories, High Tech Campus 4, 5656 AE Eindhoven, The Netherlands. fatemeh.gholamrezaie@philips.com.
Abstract:
The threshold voltage is an important property of organic field-effect transistors. By applying a self-assembled monolayer (SAM) on the gate dielectric, the value can be tuned. After electrical characterization, the semiconductor is delaminated. The surface potentials of the revealed SAM perfectly agree with the threshold voltages, which demonstrate that the shift is not due to the dipolar contribution, but due to charge trapping by the SAM.
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