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Updated: May 27, 2026
06:35
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Lithium cubane clusters as tetrahedral, square planar, and linear nodes for supramolecular assemblies
Xiang Zhao1, Tao Wu, Xianhui Bu
1Department of Chemistry, University of California, Riverside, CA 92521, USA.
Dalton Transactions (Cambridge, England : 2003)
|December 6, 2011
Summary
Bifunctional ligands containing phenol and pyridyl groups facilitate the creation of lithium cubane clusters. These clusters exhibit specific preferences for tetrahedral, square-planar, and linear hydrogen-bonding arrangements.
Area of Science:
- Supramolecular Chemistry
- Inorganic Chemistry
Background:
- Hydrogen bonding plays a crucial role in molecular assembly.
- Lithium clusters are of interest for various chemical applications.
Purpose of the Study:
- To investigate the role of bifunctional ligands in forming lithium cubane clusters.
- To explore the hydrogen-bonding preferences of these clusters.
Main Methods:
- Synthesis of lithium cubane clusters using bifunctional ligands.
- Analysis of cluster structures and hydrogen-bonding interactions.
Main Results:
- Bifunctional ligands with phenol and pyridyl groups successfully promoted lithium cubane cluster formation.
- The resulting clusters demonstrated intrinsic coding for specific hydrogen-bonding geometries.
- Observed hydrogen bonding modes included tetrahedral, square-planar, and linear arrangements.
- Double and quadruple hydrogen bonding interactions were identified between adjacent nodes.
Conclusions:
- Bifunctional ligands are effective in directing the self-assembly of lithium cubane clusters.
- The ligand design influences the specific hydrogen-bonding geometries adopted by the clusters.
- This work provides insights into controlling supramolecular architecture through ligand design.
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