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Cyclodextrin induced switch between heterolytic and homolytic dediazoniation mechanisms

Alejandra Fernández-Alonso1, Carlos Bravo-Díaz

  • 1Universidad de Vigo, Facultad de Química, Dpt. Química Física, 36200 Vigo, Spain.

Journal of Colloid and Interface Science
|December 14, 2011
PubMed
Summary

The addition of cyclodextrins (CDs) accelerates the dediazoniation of 4-nitrobenzenediazonium (4NBD) and shifts the reaction mechanism from heterolytic to homolytic pathways, favoring reduction products.

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