Related Experiment Video
Updated: May 26, 2026

Characterization of Thermal Transport in One-dimensional Solid Materials
Published on: January 26, 2014
Universality classes for phonon relaxation and thermal conduction in one-dimensional vibrational systems
1Department of Physics, Indian Institute of Technology Madras, Chennai 600036, Tamil Nadu, India.
Abstract:
We study phonon relaxation in chains of particles coupled through polynomial-type pair-interaction potentials and obeying quantum dynamics. We present detailed calculations for the sixth-order potential and find that the wave-vector-dependent relaxation rate follows a power-law behavior, Γ(q)∼q(δ), with δ=5/3, which is identical to that of the fourth-order potential. We argue through diagrammatic analysis that this is a generic feature of even-power potentials. Our earlier analysis has shown that δ=3/2 when the leading-order term in the nonlinear potential is odd, suggesting that there are two universality classes for the phonon relaxation rates dependent on a simple property of the potential. This implies that the thermal conductivity κ which diverges as a function of chain size N as κ∝N(α) also has two universal behaviors, in that α=1-1/δ as follows from a finite-size argument. We support these arguments by numerical calculations of conductivity for chains obeying classical dynamics for polynomial potentials of some even and odd powers.
Related Concept Videos
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
According to Hooke's law, the vibrational frequency is directly proportional to the...
First Law: Particles in One-dimensional Equilibrium
Thermal Sigmatropic Reactions: Overview
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
Dimensionless Groups in Fluid Mechanics
Thermodynamic Systems
Consider an example of tea boiling in a kettle. The tea and...

