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Related Experiment Video

Updated: May 26, 2026

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

Direct nanorod assembly using block copolymer-based supramolecules.

Kari Thorkelsson1, Alexander J Mastroianni, Peter Ercius

  • 1Department of Materials Science and Engineering, University of California, Berkeley, California, USA.

Nano Letters
|December 23, 2011
PubMed
Summary
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Precise control over one-dimensional nanomaterial organization is achieved using block copolymer (BCP) supramolecules. This method enables tailored nanorod dispersal and alignment for advanced optical and electronic nanodevices.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Polymer Chemistry

Background:

  • Controlling the organization of one-dimensional nanomaterials is crucial for developing functional materials.
  • Collective properties of nanomaterials depend on their spatial arrangement, interparticle ordering, and macroscopic alignment.

Purpose of the Study:

  • To investigate the coassembly of nanorods and block copolymer (BCP)-based supramolecules.
  • To achieve precise control over nanorod dispersion, inter-rod ordering, and alignment within BCP microdomains.

Main Methods:

  • Systematic investigation of nanorod-BCP supramolecular coassemblies.
  • Tailoring energetic contributions from nanorod ligand-polymer interactions, polymer chain deformation, and rod-rod interactions.
  • Varying supramolecular morphology and chemical nature of nanorods.

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Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
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Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
08:40

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules

Published on: April 28, 2014

Related Experiment Videos

Last Updated: May 26, 2026

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
11:42

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
08:40

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules

Published on: April 28, 2014

Main Results:

  • Energetic contributions are comparable and can be tailored for controlled nanorod organization.
  • Achieved nanoscopic networks of nanorods.
  • Obtained nanorod arrays parallel to cylindrical BCP microdomains.

Conclusions:

  • Supramolecular approach offers precise morphological control in nanorod-containing nanocomposites.
  • This method is applicable for fabricating advanced optical and electronic nanodevices.