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Updated: May 26, 2026
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
N,N,N',N'-Tetra-methyl-N,N'-dipropyl-ethane-1,2-diaminium tetra-chlorido-cobaltate(II)
Sari M Närhi1, Jatta Kostamo, Janne Asikkala
1Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland.
Abstract:
The crystal structure of the title compound, (C(12)H(30)N(2))[CoCl(4)], is composed of discrete (C(12)H(30)N(2))(2+) cations and [CoCl(4)](2-) anions. The asymmetric unit contains a half-cation and a half-anion. The atoms of the cation occupy general positions about an inversion centre, which is located at the midpoint of the central C-C bond. The Co atoms lie on a twofold rotation axis. The slightly distorted tetra-hedral coordination environment around the metal atom consists of two Cl atoms and their symmetry-related pairs.
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