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Updated: May 26, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
catena-Poly[[copper(II)-bis-[μ-bis-(pyridin-3-yl)methanone-κN:N']] bis-(tetra-fluorido-borate)]
1Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.
Abstract:
In the title complex, {[Cu(C(11)H(8)N(2)O)(2)](BF(4))(2)}(n), the Cu(II) ion is situated on an inversion centre and adopts an N(4)F(2) octa-hedral coordination geometry with four N atoms from four different bis-(pyridin-3-yl)methanone ligands at the equatorial sites and two independent tetra-fluoridoborate anions weakly bonded at the axial sites via two F atoms [Cu⋯F = 2.613 (3) Å]. Chains with the bridging ligands are formed along the a axis. C-H⋯F inter-actions stabilize the structure. C-O⋯π inter-actions also occur.
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