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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
N-(3,5-Dimethyl-phen-yl)-4-methyl-benzamide
Acta Crystallographica. Section E, Structure Reports Online
|December 27, 2011
Summary
This study details the crystal structure of a novel organic compound, C(16)H(17)NO. The structure is characterized by a specific dihedral angle between benzene rings and is stabilized by intermolecular hydrogen bonds forming molecular chains.
Area of Science:
- Crystallography
- Organic Chemistry
- Materials Science
Background:
- Understanding molecular interactions is crucial for designing new materials.
- Crystal structure analysis provides insights into intermolecular forces.
Purpose of the Study:
- To determine the crystal structure of the compound C(16)H(17)NO.
- To investigate the intermolecular interactions stabilizing the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to analyze the crystal structure.
- Analysis of bond lengths, bond angles, and intermolecular contacts.
Main Results:
- The dihedral angle between the two benzene rings in C(16)H(17)NO was determined to be 16.6(1)°.
- Intermolecular N-H⋯O hydrogen bonds were identified as the primary stabilizing forces.
- These hydrogen bonds link the molecules into chains along the c axis.
Conclusions:
- The crystal structure of C(16)H(17)NO is characterized by a defined dihedral angle and is stabilized by a network of hydrogen bonds.
- The observed hydrogen bonding pattern dictates the formation of one-dimensional molecular chains.
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