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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
Published on: May 26, 2019
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Isopropyl-triphenyl-phospho-nium bromide monohydrate
Hai Wang1, Xi-Man Zhang, Ping Li
1School of Chemistry and Chemical Engineering, TaiShan Medical University, Tai'an 271016, People's Republic of China.
Acta Crystallographica. Section E, Structure Reports Online
|December 27, 2011
Summary
This study details the crystal structure of a water-solvated salt, C(21)H(22)P(+)·Br(-)·H(2)O. It highlights hydrogen bonding interactions between ionic components, water molecules, and bromide anions.
Area of Science:
- Crystal chemistry
- Supramolecular chemistry
- Solid-state chemistry
Background:
- Understanding the role of water in ionic salt structures is crucial.
- Investigating intermolecular interactions provides insights into material properties.
Purpose of the Study:
- To elucidate the crystal structure of the water-solvated salt C(21)H(22)P(+)·Br(-)·H(2)O.
- To analyze the hydrogen bonding network within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of intermolecular contacts, including hydrogen bonds (C-H⋯Br, O-H⋯O, O-H⋯Br), was performed.
Main Results:
- The crystal structure reveals the arrangement of the ionic components (C(21)H(22)P(+) and Br(-)) and water molecules.
- Short C-H⋯Br contacts link the ionic species along the a-axis.
- Half-occupied water molecules form strong O-H⋯O hydrogen bonds and interact with bromide anions via O-H⋯Br contacts.
Conclusions:
- The crystal structure of C(21)H(22)P(+)·Br(-)·H(2)O is characterized by a specific hydrogen bonding network.
- Water molecules play a significant role in stabilizing the crystal lattice through interactions with both cations and anions.
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