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Updated: May 26, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Low-temperature superstructure of [(N,N-diisobutyl-carbamo-yl)meth-yl]oct-yl(phen-yl)phosphine oxide (CMPO)
Abstract:
At 120 K, the title compound, C(24)H(42)NO(2)P, crystallizes in a unit cell with a doubled a parameter compared with the room-temperature structure. There are four mol-ecules in the asymmetric unit, one of which shows extensive disorder in a 0.588 (3):0.412 (3) ratio. In the crystal, numerous C-H⋯O inter-actions link the mol-ecules.
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