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Antisymmetric exchange in triangular tricopper(II) complexes: correlation among structural, magnetic, and electron

Sacramento Ferrer1, Francesc Lloret, Emilio Pardo

  • 1Departament de Química Inorgànica, Universitat de València, Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain. sacramento.ferrer@uv.es

Inorganic Chemistry
|January 7, 2012
PubMed
Summary

New trinuclear copper(II) complexes exhibit strong antiferromagnetic coupling and antisymmetric exchange, with a linear correlation found between the Cu-O-Cu angle and magnetic exchange parameters. A model predicting antisymmetric exchange in these copper triangles was also proposed.

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