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Related Concept Videos

Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...

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Updated: May 26, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
06:48

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

Patterned polymeric multilayered assemblies through hydrogen bonding and metal coordination.

Victor Piñón1, Marcus Weck

  • 1Molecular Design Institute and Department of Chemistry, New York University, 100 Washington Square East, New York, New York 10003, United States.

Langmuir : the ACS Journal of Surfaces and Colloids
|January 10, 2012
PubMed
Summary
This summary is machine-generated.

Researchers created patterned polymer assemblies using hydrogen bonding and metal coordination. These orthogonal interactions allow for individually responsive regions on the surface.

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Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes
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Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes

Published on: December 15, 2015

Area of Science:

  • Supramolecular Chemistry
  • Materials Science

Background:

  • Polymeric multilayered assemblies offer versatile platforms for advanced materials.
  • Controlling assembly and responsiveness is key for functional material design.

Purpose of the Study:

  • To develop patterned polymeric multilayered assemblies using orthogonal supramolecular interactions.
  • To demonstrate the independent responsiveness of distinct regions within the assembly.

Main Methods:

  • Utilized hydrogen bonding between diamidopyridine and thymine for initial assembly.
  • Integrated metal coordination as a second, orthogonal supramolecular interaction.
  • Fabricated multilayered structures on surfaces.

Main Results:

  • Successfully formed patterned polymeric multilayered assemblies.
  • Demonstrated the orthogonality of hydrogen bonding and metal coordination interactions.
  • Showcased that discrete regions within the assembly are individually responsive to external stimuli.

Conclusions:

  • Hydrogen bonding and metal coordination can be orthogonally combined for creating functional polymeric assemblies.
  • The developed method allows for precise control over material patterning and responsiveness.