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Spatial variability and application of ratios between BTEX in two Canadian cities
Lindsay Miller1, Xiaohong Xu, Amanda Wheeler
1Department of Civil and Environmental Engineering, University of Windsor, Windsor, ON, Canada N9B 3P4.
Benzene, toluene, ethylbenzene, and xylenes (BTEX) levels were similar in Windsor and Sarnia, but local industries influenced their ratios. Using multiple BTEX ratios improves photochemical age assessment, especially near industrial sources.
Area of Science:
- Environmental Science
- Atmospheric Chemistry
- Urban Air Quality
Background:
- Volatile organic compounds (VOCs) are significant air pollutants in urban industrial areas.
- Benzene, toluene, ethylbenzene, and xylenes (BTEX) are common VOCs with varying health impacts.
- Understanding BTEX distribution and ratios is crucial for assessing urban air quality and photochemical processes.
Purpose of the Study:
- To compare BTEX concentrations and species relationships in two Canadian urban industrial cities, Windsor and Sarnia.
- To investigate the influence of local industries and land use on BTEX ratios.
- To evaluate the reliability of BTEX ratios for diagnosing photochemical age in industrial urban environments.
Main Methods:
- Conducted spatial monitoring campaigns using passive 3M 3500 organic vapor samplers.
- Collected data across multiple seasons in Windsor (2004-2006) and during fall in Sarnia (2005).
- Analyzed BTEX concentrations and calculated ratios between species, correlating them with land use data.
Main Results:
- BTEX concentration levels and species rank order were similar in both Windsor and Sarnia during fall sampling.
- BTEX species relationships varied spatially in Sarnia, indicating strong local industrial influence.
- Correlation analysis revealed significant impact of land use on BTEX ratios, suggesting potential bias in photochemical age diagnostics from single ratios.
Conclusions:
- While overall BTEX levels were comparable, local industrial emissions significantly affected BTEX species ratios in Sarnia.
- Using multiple BTEX ratios provides more reliable insights into photochemical aging than single ratios, especially in industrially impacted areas.
- Spatial monitoring data revealed deviations from central monitoring stations, highlighting the importance of localized sampling for accurate air quality assessment.
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