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Published on: October 25, 2013
Highly sensitive and selective detection of beryllium ions using a microcantilever modified with benzo-9-crown-3
Rong-Peng Peng1, Bin Chen, Hai-Feng Ji
1Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Abstract:
A microcantilever sensor modified by chitosan/gelatin hydrogels that are doped with benzo-9-crown-3 has been developed for the sensitive and selective detection of beryllium ions in an aqueous solution. The microcantilever undergoes bending deflection upon exposure to Be(2+) due to selective absorption of Be(2+) in the hydrogel. The detection limit is 10(-11) M. Other metal ions, such as Li(+), Na(+), K(+), Mg(2+), and Ca(2+), have a marginal effect on the deflection of the microcantilever. The mechanism of the bending is discussed and the results showed that the microcantilever may be used for in situ detection of beryllium.

