Related Experiment Video
Updated: May 25, 2026

On-chip Isotachophoresis for Separation of Ions and Purification of Nucleic Acids
Published on: March 2, 2012
Do anions influence the polarity of protic ionic liquids?
Shashi Kant Shukla1, Nageshwar D Khupse, Anil Kumar
1Physical Chemistry Division, National Chemical Laboratory, Pune 411 008, India.
Abstract:
Polarity studies in two classes of imidazolium-based protic ionic liquids (PILs) possessing [HSO(4)](-), [HCOO](-), [CH(3)COO](-) and [CH(3)CH(2)COO](-) anions were carried out using a solvatochromic method from 298.15 to 353.15 K. For 1-methylimidazolium class of PILs, E(T)(30) was found to be independent over the entire range of temperature, while E(T)(30) was noted to decrease with a rise in temperature in the case of 1-butylimidazolium class of PILs containing [CH(3)COO](-) and [CH(3)CH(2)COO](-) anions. The E(T)(30) value decreases in both the classes upon varying the anions ([HSO(4)](-), [HCOO](-), [CH(3)COO](-) and [CH(3)CH(2)COO](-)). The E(T)(30) value is controlled by hydrogen bond acceptor basicity, β, and dipolarity/polarizability, π*. The E(T)(30) value for PILs varies inversely to the strength of the coulombic interaction between ions in PILs. Strong interactions between ions lead to lower E(T)(30) values. Unlike the poor thermal effect on E(T)(30), the Kamlet-Taft parameters i.e. α, β and π* have pronounced thermal effect in the imidazolium-based PILs. Variation in the Kamlet-Taft parameters is controlled by the stabilization of ions and the degree of proton transfer from Brønsted acid to Brønsted base.
More Related Videos
11:04Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
08:06Merging Ion Concentration Polarization between Juxtaposed Ion Exchange Membranes to Block the Propagation of the Polarization Zone
Published on: February 23, 2017
Related Concept Videos
Intermolecular Forces
Ionic Association
Solvating Effects
Bond Polarity, Dipole Moment, and Percent Ionic Character
Molecular Shape and Polarity
Theory of Strong Electrolytes