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In situ formed white-light-emitting lanthanide-zinc-organic frameworks
Shu-Mu Li1, Xiang-Jun Zheng, Da-Qiang Yuan
1College of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
Inorganic Chemistry
|January 26, 2012
Abstract:
Five novel 3D heterometallic lanthanide-zinc-organic frameworks, [H(H(2)O)(8)][LnZn(4)(imdc)(4)(Him)(4)] [Ln = La (1), Pr (2), Eu (3), Gd (4), Tb (5); H(3)imdc = 4,5-imidazoledicarboxylic acid; Him = imidazole], were synthesized via an in situ hydrothermal reaction, and tunable luminescence from yellow to white was obtained through the doping of Eu and Tb ions in the La-Zn framework.
