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Dynamic nuclear polarization with a water-soluble rigid biradical

Matthew K Kiesewetter1, Björn Corzilius, Albert A Smith

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|March 1, 2012
PubMed
Summary

A novel biradical polarizing agent, bTbtk-py, significantly enhances dynamic nuclear polarization (DNP) NMR signal in aqueous solutions. This new agent achieves the largest signal enhancement reported for biradicals in a specific glycerol/water matrix.

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