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Guest-responsive reversible swelling and enhanced fluorescence in a super-absorbent, dynamic microporous polymer
K Venkata Rao1, Sudip Mohapatra, Tapas Kumar Maji
1Supramolecular Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Jakkur P.O., Bangalore 560064, India.
Abstract:
A swell idea! The guest-responsive reversible swelling and fluorescence enhancement of a dynamic, microporous polymer network is presented. Guest-induced breathing of hydrophobic pores imparts multi-functional properties, such as super-absorbency, phase-selective swelling of oil from water and encapsulation of C(60) (see figure), to this soft micro-porous organic polymer.
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