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Updated: May 24, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Bis(μ-propan-2-olato-κO:O)bis-[chlor-ido(propan-2-ol-κO)bis-(pro-pan-1-ol-ato-κO)tin(IV)]
Abstract:
The binuclear centrosymmetric title compound, [Sn(2)(C(3)H(7)O)(6)Cl(2)(C(3)H(8)O)(2)], exhibits an edge-shared double octahedral exhibits an edge-shared octa-hedral structure, which is distorted owing to the presence of asymmetric intra-molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy-droxy group is located nearer to an isoprop-oxy group with the longest Sn-O bond [2.1789 (17) Å].
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