Related Experiment Video
Updated: May 24, 2026

Phase-Dependent Control of Trap Depth and Persistent Luminescence in Strontium Aluminate Phosphors
Published on: December 5, 2025
Structure, charge-transfer and luminescent properties bis(2-methyl-8-hydroxyquinoline) gallium chloride
Liuqing Chen1, Xuguang Liu, Bingshe Xu
1Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan, Shanxi, 030024, China.
Abstract:
Bis(2-methyl-8-hydroxyquinoline) Gallium Chloride (GaMq2Cl) has been synthesized and characterized by X-ray crystallography. It is known from X-ray diffraction data on single crystals that the crystals of GaMq2Cl were monoclinic, space group C2/c, a = 28.701 A, b = 9.5405 A, c = 15.1434 A, Z = 8. Its thermal stability, electron structures and structural stability were investigated by TG analysis and quantum chemical calculations. The complex was a thermally stable material, with decomposition temperature being 348 degrees C. The electron-transfer property of GaMq2Cl is of advantage over hole-transfer property. Under UV excitation at 365 nm, the complex emits blue fluorescence with the maximum emission peak at 471 nm. Finally, blue-green light-emitting devices using this complex as the emissive layer were also fabricated and investigated, with emission wavelength at 502 nm. The results promote GaMq2Cl as a good candidate for luminescent material.
Related Concept Videos
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Photoluminescence: Applications
Valence Bond Theory
Photoluminescence: Fluorescence and Phosphorescence
A pair of electrons in a...
Variables Affecting Phosphorescence and Fluorescence
Ionic Bonding and Electron Transfer

