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Hydrido(hydrosilylene)tungsten complexes: dynamic behavior and reactivity toward acetone.

Takahito Watanabe1, Hisako Hashimoto, Hiromi Tobita

  • 1Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan.

Chemistry, an Asian Journal
|March 24, 2012
PubMed
Summary

Tungsten nitrile complexes react with silicon hydrides to form hydrido(hydrosilylene) tungsten complexes. These complexes exhibit strong interligand interactions and undergo facile H/D exchange, particularly under UV light, and react with acetone via hydrosilylation or alpha-H abstraction.

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