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Updated: May 23, 2026

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Porous double-walled metal triazolate framework based upon a bifunctional ligand and a pentanuclear zinc cluster
Wen-Yang Gao1, Wuming Yan, Rong Cai
1Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, Florida 33620, USA.
Abstract:
The self-assembly of a custom-designed bifunctional ligand featuring both 1,2,3-triazolate and carboxylate donor groups with a pentanuclear zinc cluster generated in situ affords a double-walled metal triazolate framework (MTAF) material, MTAF-1 (Zn(5)(μ(3)-O)(2)(C(9)N(3)H(5)O(2))(5)(H(+))(4)(H(2)O)(17)(C(3)H(7)NO)(10)), which exhibits a surface area of 2300 m(2)/g and demonstrates interesting selective CO(2) uptake performances.
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