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Updated: May 23, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes
Adrián Gómez-Suárez1, Rubén S Ramón, Alexandra M Z Slawin
1EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK.
Abstract:
New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(μ-OH)][BF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.
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