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Updated: May 23, 2026

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Published on: June 23, 2023
Ethanol isotope method (EIM) for uncovering illegal wine
I Smajlović1, K L Sparks, J P Sparks
1SG Isotech Inc, 1529 Oakwood Ave, Des Plaines, IL 60016, USA. ivan@sgisotech.com
This study introduces a new isotopic method to detect wine adulteration. The technique accurately identifies added water and sugar, ensuring wine authenticity and quality.
Area of Science:
- Analytical Chemistry
- Food Science
- Organic Chemistry
Background:
- Isotopic methods are crucial for verifying wine origin and authenticity.
- Stable isotope ratio analysis aids in detecting fraudulent wine production practices.
- Isotope ratio mass spectrometry is the standard for measuring stable isotope compositions.
Purpose of the Study:
- To present a novel isotopic method for analyzing non-exchangeable hydrogen stable isotopes in wine ethanol.
- To enhance the detection accuracy of adulteration practices in winemaking.
- To improve the reliability and repeatability of authenticity testing.
Main Methods:
- Development of a new isotopic method for measuring the deuterium (δD) value.
- Focus on non-exchangeable hydrogen stable isotopes in ethanol.
- Utilizing isotope ratio mass spectrometry for precise measurements.
Main Results:
- The new method offers higher accuracy in detecting water and sugar addition.
- Demonstrated improved repeatability and reliability in identifying adulteration.
- Provides a more robust tool for wine authenticity analysis.
Conclusions:
- The developed isotopic method is effective for investigating wine adulteration.
- This technique enhances the ability to ensure wine authenticity and prevent fraud.
- Offers a significant advancement in analytical methods for the wine industry.
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