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Updated: May 23, 2026

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
Published on: April 12, 2019
Ru complexes containing pyridine dicarboxylate ligands: electronic effects on their catalytic activity toward water
Junxue An1, Lele Duan, Licheng Sun
1Department of Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), 100 44 Stockholm, Sweden.
Abstract:
Two series of mononuclear ruthenium complexes [Ru(pdc)L3] (H2pdc = 2,6-pyridinedicarboxylic acid; L = 4-methoxypyridine, 1; pyridine, 2; pyrazine, 3) and [Ru(pdc)L2(dmso)] (dmso = dimethyl sulfoxide; L = 4-methoxypyridine, 4; pyridine, 5) were synthesized and spectroscopically characterized. Their catalytic activity toward water oxidation has been examined using Ce(IV) (Ce(NH4)2(NO3)6) as the chemical oxidant under acidic conditions. Complexes 1, 2 and 3 are capable of catalyzing Ce(IV)-driven water oxidation while 4 and 5 are not active. Electronic effects on their catalytic activity were illustrated: electron donating groups increase the catalytic activity.
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