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Design, Fabrication, and Experimental Characterization of Plasmonic Photoconductive Terahertz Emitters
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Far-infrared properties of hybrid plasmonic geometries

Xinchao Lu1, Carsten Rockstuhl, Weili Zhang

  • 1School of Electrical and Computer Engineering, Oklahoma State University, Stillwater, Oklahoma 74078, USA.

Journal of the Optical Society of America. A, Optics, Image Science, and Vision
|April 5, 2012
PubMed

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Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...