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Synthesis of cyclopropyl glycosides and their use as novel glycosyl donors

Clark Scholl1, Thomas Licisyn, Christopher Cummings

  • 1Department of Chemistry, Villanova University, Villanova, PA 19085, USA.

Carbohydrate Research
|April 6, 2012
PubMed

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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