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Updated: May 23, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
Published on: October 3, 2014
Coordination of phosphinoboranes R2PB(C6F5)2 to platinum: an alkene-type behavior
Abderrahmane Amgoune1, Sonia Ladeira, Karinne Miqueu
1Université de Toulouse , UPS, LHFA, 118 Route de Narbonne, F-31062 Toulouse, France. amgoune@chimie.ups-tlse.fr
Abstract:
The paucity of boron-containing heteroalkene complexes prompted us to explore the coordination of phosphinoboranes. The complexes {[R(2)PB(C(6)F(5))(2)]Pt(PPh(3))(2)} (R = Cy, t-Bu) were obtained by ethylene displacement. Spectroscopic and crystallographic data indicated symmetric side-on coordination of the phosphinoborane to Pt. Thorough analysis of the bonding situation by computational means revealed important similarities but also significant differences between the phosphinoborane and ethylene complexes.
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