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Updated: May 23, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
A chiral quadruple-stranded helicate cage for enantioselective recognition and separation
Weimin Xuan1, Mengni Zhang, Yan Liu
1School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.
Abstract:
The self-assembly of enantiopure pyridyl-functionalized metallosalan units affords a homochiral helicate cage, [Zn(8)L(4)Cl(8)], in which the optical rotation of each ligand is increased by a factor of 10 upon coordination. The octanuclear cage featuring a chiral amphiphilic cavity exhibits enantioselective luminescence enhancement by amino acids in solution. The cage exists in two different crystalline polymorphic forms that possess porous structures built of helicate cages interconnected by 1D channels or pentahedral cages and have the ability to separate small racemic molecules by adsorption but with different enantioselectivities.
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