Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

X-ray Crystallography02:18

X-ray Crystallography

The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
Determination of Crystal Structures01:29

Determination of Crystal Structures

In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A reference material for X-ray diffraction line profile analysis.

Journal of applied crystallography·2025
Same author

Correction: Thermoelectric properties of CZTS thin films: effect of Cu-Zn disorder.

Physical chemistry chemical physics : PCCP·2021
Same author

Thermoelectric properties of CZTS thin films: effect of Cu-Zn disorder.

Physical chemistry chemical physics : PCCP·2021
Same author

Simulating the diffraction line profile from nanocrystalline powders using a spherical harmonics expansion.

Acta crystallographica. Section A, Foundations and advances·2018
Same author

Size-strain separation in diffraction line profile analysis.

Journal of applied crystallography·2018
Same author

Mechanical activation of Efavirenz: the effects on the dissolution and inhibitory behavior.

Pharmaceutical development and technology·2018
Same journal

Report of the Executive Committee for 2006.

Acta crystallographica. Section A, Foundations of crystallography·2020
Same journal

Spin line groups.

Acta crystallographica. Section A, Foundations of crystallography·2013
Same journal

Distribution rules of systematic absences on the Conway topograph and their application to powder auto-indexing.

Acta crystallographica. Section A, Foundations of crystallography·2013
Same journal

Platonic solids generate their four-dimensional analogues.

Acta crystallographica. Section A, Foundations of crystallography·2013
Same journal

C70, C80, C90 and carbon nanotubes by breaking of the icosahedral symmetry of C60.

Acta crystallographica. Section A, Foundations of crystallography·2013
Same journal

Comparative study of X-ray charge-density data on CoSb3.

Acta crystallographica. Section A, Foundations of crystallography·2013
See all related articles

Related Experiment Video

Updated: May 23, 2026

Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model
06:54

Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model

Published on: August 22, 2015

Temperature diffuse scattering of nanocrystals.

K R Beyerlein1, M Leoni, P Scardi

  • 1Materials Science and Engineering Department, Georgia Institute of Technology, Atlanta, GA, USA. kbeyerlein3@gatech.edu

Acta Crystallographica. Section A, Foundations of Crystallography
|April 20, 2012
PubMed
Summary
This summary is machine-generated.

Accurate modeling of temperature diffuse scattering (TDS) is crucial for interpreting X-ray powder diffraction data, especially for small crystallites. Misrepresenting TDS can cause significant errors in the Debye-Waller parameter and peak broadening analysis.

More Related Videos

Characterization of Ultra-fine Grained and Nanocrystalline Materials Using Transmission Kikuchi Diffraction
09:13

Characterization of Ultra-fine Grained and Nanocrystalline Materials Using Transmission Kikuchi Diffraction

Published on: April 1, 2017

Utilization of Plasmonic and Photonic Crystal Nanostructures for Enhanced Micro- and Nanoparticle Manipulation
09:29

Utilization of Plasmonic and Photonic Crystal Nanostructures for Enhanced Micro- and Nanoparticle Manipulation

Published on: September 27, 2011

Related Experiment Videos

Last Updated: May 23, 2026

Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model
06:54

Characterization of Nanocrystal Size Distribution using Raman Spectroscopy with a Multi-particle Phonon Confinement Model

Published on: August 22, 2015

Characterization of Ultra-fine Grained and Nanocrystalline Materials Using Transmission Kikuchi Diffraction
09:13

Characterization of Ultra-fine Grained and Nanocrystalline Materials Using Transmission Kikuchi Diffraction

Published on: April 1, 2017

Utilization of Plasmonic and Photonic Crystal Nanostructures for Enhanced Micro- and Nanoparticle Manipulation
09:29

Utilization of Plasmonic and Photonic Crystal Nanostructures for Enhanced Micro- and Nanoparticle Manipulation

Published on: September 27, 2011

Area of Science:

  • Materials Science
  • Crystallography
  • Solid-State Physics

Background:

  • Thermal vibrations significantly influence diffraction patterns.
  • Understanding these effects is vital for accurate crystallographic analysis.
  • Small crystallites exhibit unique vibrational behaviors.

Purpose of the Study:

  • To present a comprehensive model for temperature diffuse scattering (TDS) in X-ray powder diffraction.
  • To investigate the impact of crystallite size and temperature on TDS.
  • To highlight the importance of accurate TDS for determining material properties.

Main Methods:

  • Development of a complete TDS model accounting for surface and edge vibrational modes.
  • Analysis of the influence of these modes on Debye-Waller parameter and higher-order TDS terms.
  • Examination of TDS effects as a function of temperature and crystallite size.

Main Results:

  • A complete TDS model is presented, incorporating effects specific to small crystallites.
  • Errors in the Debye-Waller parameter can reach 20-40% if TDS is misrepresented for small crystallites.
  • Peak broadening may be slightly overestimated due to inaccurate TDS representation.

Conclusions:

  • Accurate TDS modeling is essential for precise crystallographic analysis, particularly for nanomaterials.
  • The developed TDS model provides a more reliable framework for interpreting X-ray diffraction data.
  • The theoretical framework is applicable to both X-ray and neutron powder diffraction.