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Aphanamixoid A, a potent defensive limonoid, with a new carbon skeleton from Aphanamixis polystachya

Jie-Yun Cai1, Yu Zhang, Shi-Hong Luo

  • 1State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, Yunnan, P. R. China, and Graduate School of Chinese Academy of Sciences, Beijing 100039, P. R. China.

Organic Letters
|May 1, 2012
PubMed

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.
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