Buoyancy-driven convection may switch between reactive states in three-dimensional chemical waves

Traveling waves in an extended reactor, whose width cannot be neglected, represent a three-dimensional (3D) reaction-diffusion-convection system. We investigate the effects of buoyancy-driven convection in such a setting. The 3D waves traveled through horizontal layers of the iodate-arsenous acid (IAA) reaction solution containing excess of arsenous acid. The depth of the reaction solution was the examined parameter. An increase in the intensity of buoyancy-driven flow caused an increase of the traveling wave velocities. Convection distorted the front of the chemical waves. For layers deeper than h>13 mm, heat release became smaller than heat production causing the emergence of Rayleigh-Bénard convection cells. At the interface, a dependency of wave shape on solution depth was observed. For h<7 mm, the waves adopted a stable V-like shape, while for h>13 mm a parabolic shape dominated. For 7