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Updated: May 22, 2026
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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
(R)-2,2'-Bis(meth-oxy-meth-oxy)-1,1'-binaphth-yl
1The Key Laboratory of Applied Catalysis, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi, Xinjiang 830011, People's Republic of China.
Summary
This study details the crystal structure of C(24)H(22)O(4), revealing two independent molecules with transoid naphthalene ring systems. Weak C-H⋯O hydrogen bonds were observed in the crystal lattice.
Area of Science:
- Crystallography
- Organic Chemistry
- Molecular Structure
Background:
- Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties and reactivity.
- The naphthalene moiety is a common structural motif in various organic compounds with diverse applications.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(24)H(22)O(4).
- To analyze the molecular geometry, including dihedral angles and torsion angles, of the independent molecules.
- To identify intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the crystal structure.
- The asymmetric unit was analyzed to identify independent molecules and their conformations.
- Geometric parameters such as dihedral and torsion angles were calculated.
Main Results:
- The asymmetric unit contains two independent molecules of C(24)H(22)O(4).
- Both molecules exhibit a transoid arrangement of their naphthalene ring systems, with dihedral angles of 83.0(1)° and 89.0(1)°.
- Slight variations were noted in the torsion angles of the methoxy-methoxy groups.
- Weak C-H⋯O hydrogen bonds were identified as the primary intermolecular interactions.
Conclusions:
- The crystal structure of C(24)H(22)O(4) has been successfully determined.
- The study provides detailed insights into the conformational preferences of the naphthalene ring systems and methoxy-methoxy groups.
- The presence of weak hydrogen bonds influences the crystal packing.
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