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Switching Kr/Xe selectivity with temperature in a metal-organic framework

Carlos A Fernandez1, Jian Liu, Praveen K Thallapally

  • 1Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.

Journal of the American Chemical Society
|May 18, 2012
PubMed

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...