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Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
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Hexanuclear copper(II) cages built on a central {μ3-O···H···μ3-O} moiety, 1,3-bis(dimethylamino)-2-propanolato and

Saskia Speed1, Ramon Vicente, Daniel Aravena

  • 1Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain.

Inorganic Chemistry
|May 26, 2012
PubMed

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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