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Updated: May 21, 2026
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
In situ synthesis of nickel tiara-like clusters with two different thiolate bridges
Chunhong Tan1, Meiliang Jin, Xiao Ma
1State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China.
Abstract:
Four nickel clusters, cyclo-[{Ni(μ-S(i)Pr)(μ-SMe)}(6)] (1), cyclo-[{Ni(μ-StBu)(μ-SMe)}(6)] (2), cyclo-[{Ni(μ-S(i)Pr)(μ-SEt)}(6)] (3) and cyclo-[{Ni(μ-StBu)(μ-SEt)}(10)] (4), based on thiolate ligands have been successfully synthesized and characterized by elemental analysis, FT-IR spectra, UV-vis-NIR spectra, powder X-ray diffraction and single-crystal X-ray diffraction. Intriguingly, the SMe and SEt ligands are generated from solvothermal in situ ligand synthesis through the cleavage of the S-S bond respectively. The four nickel thiolate clusters exhibit tiara-like frameworks consisting of two different types of thiolate ligands.
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