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Updated: May 21, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Sevenfold enhancement on porphyrin dye efficiency by coordination of ruthenium polypyridine complexes
André L A Parussulo1, Bernardo A Iglesias, Henrique E Toma
1Instituto de Química, Universidade de Sao Paulo, Av. Lineu Prestes 748, Butanta, Sao Paulo, SP 05508-000, Brazil.
Abstract:
Sevenfold enhancement of photoconversion efficiency was achieved by incorporation of peripheral ruthenium complexes to a porphyrin dye, generating supramolecular effects capable of playing several key roles (e.g., transferring energy to, inhibiting aggregation, and accepting the hole generated in the porphyrin center after electron injection), providing new insights for the design of better DSSC photosensitizers.
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