EPR studies on branched high-spin arylnitrenes

Sergei V Chapyshev1, Denis V Korchagin, Mikhail F Budyka

  • 1Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russia. chap@icp.ac.ru

Summary

UV photolysis of triazide selectively produces triplet mononitrene, quintet dinitrene, and septet trinitrene. Dinitrene and trinitrene are the major products, with rotational isomers influencing magnetic parameters and EPR spectra.

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